No such file or directory

Hello, im using codeblocks and when I try to compile it gives me this error :

http://i.imgur.com/X5ul5R6.png

This is my Toolchain executables settings :

http://i.imgur.com/6WYtEQD.png

How can I fix it? I'm searching for the answer whole day, but I can't find a way to do that..
What happens if you save the file before compiling it?
You mean "Save file as" or "Build"? If I try "Save file as" it saves my file in my folder. What happen when I use "Build" You can see in this photo : http://i.imgur.com/X5ul5R6.png
In the image the filename has an asterisk in front which usually means the file has been modified but not saved so I just thought that maybe the file have not been created at all but if that is not the case I don't know. I must say the error message is not very helpful, unfortunately.
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