I'm beginner and I want to self study Visual C++ (MFC) using Visual Studio 2010.
can you suggest me any Book that can have all the programming codes and stuff.
MFC is still MFC. The best beginner's book on it I ever found is still Jeff Prosise's "Programming Windows 95 with MFC". It contains nothing about Windows 95.
What do you think it means to "teach you VS 2010(MFC)"? VS2010 is a tool for using a compiler, that comes packaged with some helpful libraries. MFC is one of those helpful libraries. That said, it goes for 48 cents plus postage on Amazon as I type, so it's hardly a risk.
It's younger than C :) Use a good tool for the job; age doesn't matter. If there are good technical (and business) reasons not to use it for a given job, that's a different story.